Counter point, maybe Barrie is getting the saves and Bouchard isn't and players can't control how good or bad a goalie is behind them.
As a goalie: yes you can.
Everything, and I mean everything you do impacts my ability to make that save. It's all 100% about angles, sight-lines and pressure. A good, experienced defender can give up just as many "high danger" chances as a poor one, but if I can see it, if I know the pass isn't getting through, if the player is being rushed to get his shot off because my guy is closing him down, if half of the net is blocked by good gap control, etc, etc, etc, etc...
All of that eliminates or reduces risks and allows me to cheat toward the most likely option available to the forward. And my brain is calculating it all in real time... it will change everything about how I play the situation, how much I can cut down the angle, how much I need to respect the pass, heck even what technique I use for the save and where I try to put the rebound.
Simple example: imagine a one-on-one with a defender backing up toward his goalie.
A good defender, with a good gap will force the shot earlier AND because he has good gap, he's closer to the player, therefore I can see better, I can stay at the top of the crease and take it in the crest. The player didn't shoot for the top corners cuz he couldn't see them, so instead he tries to put it through me.
A bad defender on the same play might give more gap... back up more quickly into me and be less assertive. That means I'm coasting back faster myself because I need to be able to see around my defender. That opens up a lot of space to shoot at and once a good shooter is in good shooting range, reaction time and reflexes take a huge back seat to angles,... even the best goalie can't stop that well placed shot from deep in his crease.
None of this is to say Barrie > Bouchard or any such thing, but from the perspective of this goalie, even over time (or especially over time) xGF/GA stats can lie, GF/GA rarely do and even if they do, it doesn't matter because the reality is far more important than the expectation.
To me xGF/GA is more useful at the team level to quantify whether you are giving up more high quality chances than you are getting, or vice versa. At the individual level it comes down to the individual plays and decisions, which in my opinion map more directly to actual GF/GA.