It's not going to be exactly 1.000 but it's generally in an acceptable range close to 1.000. There has only been a handful of teams that finished a season with a PDO above 1.025 or below 0.975.
I get that it doesn't make sense. Why would Panarin scoring at one end of the rink affect Shesterkin's performance at the other end? I've said it's a bit like voodoo to me. I don't understand exactly why it works, but it seems like it does. I don't think that sv% and sh% are related, so PDO could just be an indicator. If either stat is abnormally high/low, then you are on a hot/cold streak and likely to trend towards the mean.