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Look at this freeze frame as he's about to release his 'shot'. Do you see ANYONE on the glove side of the ice? Not a single threat. There's literally nothing pre shot here, that should have been pre-scanned to say that a pass or a shot would go to the glove side of the net.
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Now the puck is just about to deflect off of Evans stick, which barely changed the direction at all, at best that puck was going middle of the net along the ice. The only option that is emerging here is a guy who would have to receive the puck on his back hand, with a Habs defender literally on his back where a stick lift would be easily performed. Even if it gets on the backhand, there's more than enough time to get out of a butterfly and push across to make that save, his stick is so far ahead of him to pick that puck up that he would have no leverage to put it in the top of the net.
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With 0 pace the puck is now sliding to the empty side of the net and the puck has no chance of getting to the net drive. Monty could try to load his glove side skate and push across and put this way, but instead decides to try to swipe at it with his stick and misses.
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The second one I will admit a bit of wrong here. Samoskevich is shooting to the glove side of the net here, but Monty's positioning is good enough here that he doesn't need an aggressive push to the glove side of the net. The side of the net option is covered and Samsokevich is showing a high glove side shot here. His elbows are up off his body, his blade is pointed to the glove and Montembeault can make a composed glove save from distance here.
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Here you can see that Montembeault, even on a shot that's reading high, look at how Samoskevich's stick is on the follow through. That shot is high, Monty is already off his glove side edge, starting a push toward the net side forward, he's guessing that Samoskevich is looking for a down low play to the side of the net rather than a shot. Shading his glove down to the ice to the point that he's actually minimized his ability to save the shot if it doesn't get deflected.
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Tipped down and into the net. If he holds his positioning on the initial shot from Samoskevich, with no loss of edge to push across, he would be more square to the deflection and easily able to get down into a butterfly with a blocker side leg extension along the ice to make the save and be able to recover on his glove side edge and get square to the open Florida player on the blocker side of the ice on the rebound.