There's so much eye test context that you can apply to individual plays that would be considered high danger chances.
Here's a classic play: the Leafs are circling the net looking for an option to walk in front but the slot is all jammed up. The kick it to the point where the two defensemen pitch it back and forth before throwing something towards the net. The goalie makes a save on the first attempt and kicks it out where a Leaf player can barely control the puck and throws another attempt towards the net, missing completely. Or there's a rebound but also 2 defensemen tying up the Leaf player and all he does is shovel the puck along the ice into the goalie's paddle down.
From an attempted shot, high danger heat map and puck possession in zone time, it checks off all the boxes. But in real time, you could break down those moments in ever greater detail. Throwing some ideas out there but 1) angle and velocity of the rebound 2) number of Leaf players in the slot, or ratio of Leaf players to defenders 3) relative body positioning, distance to the goal where the Leaf player regains control of the rebound 4) number of defensemen within the line of the rebound shot 5) the hand of the shot of the Leaf player receiving the rebound 6) the handedness of the goalie.
There are so many ways to break down that quality of scoring chance that you would have an extremely hard time trying to capture in volume. So probably why you need the stats to go with the eye test and not trust one for the other or look at the probability of things occurring.